Absorption by the atmosphere of solar radiation depends on the concentrations and spectral properties of the atmospheric constituents. Figure 23 shows a blackbody spectrum at 5750 K, representing solar irradiance at the top of the atmosphere, and a spectrum of atmospheric absorption. Absorption features due to specific gases are clear with molecular oxygen and ozone being the major absorbers in the ultraviolet and visible regions and water vapour and carbon dioxide more important in the near-infrared.
Clearly the flux at any point in the atmosphere depends on the properties and quantity of absorbing gases at higher altitudes and on the path length for the radiation, taking into account the solar zenith angle. The heights at which most absorption takes place at each wavelength can be seen in Figure 24 which shows the altitude of unit optical depth for an overhead Sun. At wavelengths shorter than 100 nm most radiation is absorbed at altitudes between 100 and 200 km by atomic and molecular oxygen and nitrogen, mainly resulting in ionized products. Solar Lyman- radiation at 121.6 nm penetrates to the upper mesosphere where it makes a significant contribution to heating rates and water vapour photolysis. Between about 80 and 120 km oxygen is photo-dissociated as it absorbs in the Schumann–Runge continuum between 130 and 175 nm. The Schumann–Runge bands, 175 – 200 nm, are associated with electronic plus vibrational transitions of the oxygen molecule and are most significant between 40 and 95 km altitude. The oxygen Herzberg continuum is found in the range 200 – 242 nm and is overlapped by the ozone Hartley–Huggins bands between 200 and 350 nm which are responsible for the photodissociation of ozone below 50 km. The ozone Chappuis bands, in the visible and near-infrared, are much weaker than the aforementioned bands but, because they absorb near the peak of the solar spectrum, the energy deposition into the atmosphere is significant. Furthermore, this deposition takes place in the lower atmosphere and so is particularly relevant for climate. The absorption of solar near-infrared by carbon dioxide and water vapour is smaller but makes an important contribution to the heat budget of the lower atmosphere.
The spectral composition of solar irradiance is thus important in determining at what altitudes it is absorbed and produces local heating.
Figure 25 presents a vertical profile of diurnally averaged solar heating rates for equatorial equinox conditions, showing the contribution of each of the UV/vis absorption bands mentioned above. This vertical structure in the absorption of solar radiation is crucial in determining the profile of atmospheric temperatures and plays an important role in atmospheric chemistry and thus composition. Not shown in Figure 25 is the contribution of near-infrared solar radiation to heating the troposphere, due to its absorption by water vapour, oxygen and minor constituents.
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