Cooling the air to saturation point is not, however, a sufficient condition for cloud to form: it is possible for the relative humidity to reach 500% without any spontaneous condensation taking place. Due to the energy associated with the surface tension of a droplet it is energetically unfavourable for a small droplet to grow and the water vapour requires a suitable surface, called a condensation nucleus, on which to condense. If the condensation nucleus is not a water surface then heterogeneous nucleation is said to take place; if it is then homogeneous nucleation occurs. In the free atmosphere, however, heterogeneous nucleation is the only important process because homogeneous nucleation requires prohibitively high relative humidities. (For a comprehensive discussion of cloud formation see the classic text by Ludlam, 1980).
Particles which act as condensation nuclei include sea salt, sulphates, mineral dust and aerosols produced from biomass burning. The concentration and composition of atmospheric aerosol vary geographically with, for example, sulphate aerosol being more abundant in the northern hemisphere as it is generated in industrial regions. A region with a higher concentration of condensation nuclei will produce a larger number of smaller cloud droplets than a remote area with clean air which will produce fewer larger droplets for the same total water content.
Smaller drops are more effective at scattering radiation so that the cloud produced in air with more aerosol has a higher albedo. An example of this can be seen in Figure 45 which shows a satellite image in which emissions of carbonaceous aerosol from ships’ funnels have modified the reflectivity of a pre-existing deck of stratocumulus cloud.
This work is licensed under a Creative Commons License.